Thanks to @Lens for creating this topic, otherwise I wouldn't have figured it out. This is a serious issue with WordOps's default WP Rocket configuration that it doesn't work well with WoCommerce installations.
There is no issue for the logged in users but suppose a Guest is browsing the site and he clicks "Add to Cart", the page will display 405 not allowed error page.
As mentioned by OP, the workaround is using Satellite NGINX Configuration which is pretty easy to do. I hope the master @VirtuBox will do the needful in the upcoming update